Identification

Data Identification:

citation:

Citation:

Title:

UKCCSRC Call 2 Project: Measurement of water solubility limits of CO2 mixtures to underpin the safe pipeline transportation of CO2

Date:

CI_Date:

Date Type:

creation

date:

2014-09

Identifier:

RS_Identifier:

code:

http://data.bgs.ac.uk/id/dataHolding/13606683

Abstract:

This Proposal focuses on the determination of the dew point of water (H2O), or “water solubility”, in impure CO2 mixtures (e.g. containing nitrogen, N2, oxygen, O2, hydrogen, H2, or mixtures of N2 + H2). The proposed work is a direct result of new findings in our project under Call 1, where we have obtained highly reproducible data for water solubility in CO2 + N2 using infrared spectroscopy and are well on the way to implementing an independent route using the so-called “Karl-Fischer” titration technique to give independent validation of our results. We have shown that the solubility of H2O is significantly reduced by the presence of even low concentrations of N2, a finding which has direct implications on anthropogenic CO2 transportation pipeline specifications and operation (e.g. internal corrosion). Such data have been identified by the Advanced Power Generation Technology Forum (APGTF) and the priorities specified in the UKCCRC Research And Pathways to Impact Delivery (RAPID) Handbook as being crucial for developing safe CO2 transportation in both the gaseous and dense phase. This Project has been designed to fill gaps in the available data, which are crucial for the safe implementation of Carbon Capture and Storage (CCS) because liquid water is highly acidic in the presence of excess CO2; this acidity can be increased by trace amounts of sulphur dioxide (SO2) and hydrogen sulphide (H2S), and this acidity will greatly accelerate corrosion in transportation pipelines and can cause further problems in sub-surface storage. Keeping water and CO2 in a single phase during transportation will largely avoid these problems. In Call 1, we set out to design and develop two complementary experimental approaches using either Infrared spectroscopy or Karl-Fischer titration. The key is now to understand the major implications for the complex range of CCS mixtures. A further complication is that the phase behaviour is highly dependent on both composition and temperature, therefore in order to fully understand the behaviour of water in the context of CCS requires further measurements. For this project we are targeting the needs outlined by National Grid in their letter for pre-combustion CCS where H2 is a likely contaminant. We have obtained preliminary data for H2 which shows that the effects may be greater than for N2, but this needs full validation. Furthermore, we propose to test the widespread assumption that the behaviour of O2 impurities will mirror that of N2. O2 is important in CCS coupled to the oxyfuel technology. Grant number: UKCCSRC-C2-185.

Point of Contact:

Responsible Party:

Individual Name:

Mike George

Organisation Name:

University of Nottingham

Contact Info:

CI_Contact:

Address:

country:

United Kingdom

e-mail:

not available

role:

pointOfContact

Responsible Party:

Individual Name:

Mike George

Organisation Name:

University of Nottingham

Contact Info:

CI_Contact:

Address:

country:

United Kingdom

e-mail:

not available

role:

principalInvestigator

Resource Maintenance:

MD_MaintenanceInformation:

maint. / update frequency:

notApplicable

Graphic overview:

Browse Graphic:

File Name:

https://resources.bgs.ac.uk/images/geonetworkThumbs/1b4ff1e4-b4e7-1c43-e054-002128a47908.png

Descriptive Keywords:

Keywords:

keyword:

http://www.eionet.europa.eu/gemet/concept?cp=13&langcode=en&ns=5

keyword:

Geology

Thesaurus Name:

Citation:

Title:

GEMET - INSPIRE themes, version 1.0

Date:

CI_Date:

date:

2008-06-01

Date Type:

publication

Keywords:

keyword:

NGDC Deposited Data

keyword:

UKCCS

keyword:

Carbon capture and storage

Thesaurus Name:

Citation:

Title:

BGS Thesaurus of Geosciences

Date:

CI_Date:

date:

2022

Date Type:

revision

Keywords:

keyword:

https://webapps.bgs.ac.uk/services/ngdc/accessions/index.html

keyword:

NGDC Deposited Data

keyword:

https://ukccs-research.org/

keyword:

UKCCS

Type:

dataCentre

Keywords:

keyword:

NERC_DDC

Resource Constraints:

MD_LegalConstraints:

Access Constraints:

otherRestrictions

Other Constraints:

intellectualPropertyRights

Other Constraints:

Either : (i) the dataset has not been formally approved by BGS for access and use by external clients under license; and / or (ii) the dataset contains 3rd party data or information obtained by BGS under terms and conditions that must be consulted before the dataset can be provided to, or accessed by, BGS staff or external clients. Refer to the BGS staff member responsible for the creation of the dataset if further advice is required. He / she should be familiar with the composition of the dataset, particularly with regard to 3rd party IPR contained in it, and any resultant access restrictions. This staff member should revert to the IPR Section (IPR@bgs.ac.uk) for advice, should the position not be clear.

Other Constraints:

http://inspire.ec.europa.eu/metadata-codelist/LimitationsOnPublicAccess/INSPIRE_Directive_Article13_1e

MD_LegalConstraints:

Use Constraints:

otherRestrictions

Other Constraints:

The copyright of materials derived from the British Geological Survey's work is vested in the Natural Environment Research Council [NERC]. No part of this work may be reproduced or transmitted in any form or by any means, or stored in a retrieval system of any nature, without the prior permission of the copyright holder, via the BGS Intellectual Property Rights Manager. Use by customers of information provided by the BGS, is at the customer's own risk. In view of the disparate sources of information at BGS's disposal, including such material donated to BGS, that BGS accepts in good faith as being accurate, the Natural Environment Research Council (NERC) gives no warranty, expressed or implied, as to the quality or accuracy of the information supplied, or to the information's suitability for any use. NERC/BGS accepts no liability whatever in respect of loss, damage, injury or other occurence however caused.

Other Constraints:

Either: (i) the dataset is made freely available, e.g. via the Internet, for a restricted category of use (e.g. educational use only); or (ii) the dataset has not been formally approved by BGS for access and use by external clients under licence, but its use may be permitted under alternative formal arrangements; or (iii) the dataset contains 3rd party data or information obtained by BGS under terms and conditions that must be consulted in order to determine the permitted usage of the dataset. Refer to the BGS staff member responsible for the creation of the dataset if further advice is required. He / she should be familiar with the composition of the dataset, particularly with regard to 3rd party IPR contained in it, and any resultant use restrictions. This staff member should revert to the IPR Section (ipr@bgs.ac.uk) for advice, should the position not be clear.

language:

eng

topicCategory:

geoscientificInformation

Extent:

Temporal Element:

TemporalExtent:

extent:

begin / end:

begin:

after

end:

before

Distribution

Distribution:

Transfer Options:

Digital Transfer Options:

onLine:

CI_OnlineResource:

linkage:

https://www.bgs.ac.uk/ukccs/accessions/projects.html

function:

information

Data Quality

Data Quality:

Scope:

DQ_Scope:

level:

nonGeographicDataset

Level Description:

MD_ScopeDescription:

other:

non geographic dataset

Report:

Domain Consistency:

Result:

Conformance Result:

specification:

Citation:

Title:

INSPIRE Implementing rules laying down technical arrangements for the interoperability and harmonisation of Geology

Date:

CI_Date:

Date Type:

publication

date:

2011

explanation:

See the referenced specification

pass:

Domain Consistency:

Result:

Conformance Result:

specification:

Citation:

Title:

Commission Regulation (EU) No 1089/2010 of 23 November 2010 implementing Directive 2007/2/EC of the European Parliament and of the Council as regards interoperability of spatial data sets and services

Date:

CI_Date:

Date Type:

publication

date:

2010-12-08

explanation:

See http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2010:323:0011:0102:EN:PDF

pass:

Lineage:

LI_Lineage:

statement:

UKCCSRC Call 2 project, grant number: UKCCSRC-C2-185, Lead institution: University of Nottingham

Metadata

File Identifier:

1b4ff1e4-b4e7-1c43-e054-002128a47908

language:

eng

Resource type:

nonGeographicDataset

Hierarchy Level Name:

non geographic dataset

Metadata Contact:

Responsible Party:

Organisation Name:

British Geological Survey

Contact Info:

CI_Contact:

phone:

CI_Telephone:

voice:

+44 131 667 1000

Address:

Delivery Point:

The Lyell Centre, Research Avenue South

city:

EDINBURGH

administrative Area:

LOTHIAN

Postal Code:

EH14 4AP

country:

United Kingdom

e-mail:

enquiries@bgs.ac.uk

role:

pointOfContact

Date Stamp:

2024-04-24

Metadata Standard Name:

http://vocab.nerc.ac.uk/collection/M25/current/GEMINI/

Metadata Standard Name:

UK GEMINI

Metadata Standard Version:

2.3

Dataset URI:

http://data.bgs.ac.uk/id/dataHolding/13606683