Vadose zone nitrate contained within cave drip waters and speleothems

This data set contains a record of nitrate concentrations and isotopic composition present within the drip waters and speleothem carbonate deposits of Cueva-cubío del Llanío, northern Spain. Data were collected between 2018 to 2020, and specifically address the nitrate composition of the cave drip waters, pool waters, rocks, soil, vegetation and contemporary speleothem carbonate. Calculations are also undertaken to assess the partitioning of nitrate between cave drip water and speleothem carbonate deposits. Data pertaining to speleothem nitrate content also extend to other cave locations (Pooles cavern, UK; Brown's Folly Mine, UK, Ease Gill Caverns, UK; Rukiesa cave, Ethiopia; Cueva Perlas, N. Spain). Sample analysis was performed at Lancaster University and the UK Centre for Ecology and Hydrology under NERC facility access grant LSMSF\CEH\L\125\11\2018. The data presented represent the full underlying dataset to Wynn et al., 2021, Chemical Geology: DOI.org/10.1016/j.chemgeo.2021.120172.
Nenalezeno https://resources.bgs.ac.uk/images/geonetworkThumbs/be32f45f-cbe2-5d1e-e054-002128a47908.png
dataset
: http://data.bgs.ac.uk/id/dataHolding/13607723
English
Geoscientific information
GEMET - INSPIRE themes, version 1.0: BGS Thesaurus of Geosciences:
Isotopes
Nitrates
Speleothems
NGDC Deposited Data
Free:
NERC_DDC
-3.5900, 43.3500, -3.5900, 43.3500
ES, ESP, GB, SPAIN [id=248000], UK [id=139300], UKM
creation: 2021-03-19
2018-01-20 - 2020-08-20
text table
University of Lancaster
Dr Peter Wynn
Lancaster Environment Centre, Lancaster, LA1 4YQ, United Kingdom
email: not available
Role: originator
University of Lancaster
Scott Ambler
Lancaster Environment Centre, Lancaster, LA1 4YQ
email: not available
Role: originator
University of Lancaster
Dr. Imke Grefe
Lancaster Environment Centre, Lancaster, LA1 4YQ
email: not available
Role: originator
UK Centre for Ecology and Hydrology
Dr. David Soto
Lancaster, LA1 4AP
email: not available
Role: originator
UK Centre for Ecology and Hydrology
Dr. Helen Grant
Lancaster, LA1 4AP
email: not available
Role: originator
British Geological Survey
Enquiries
email: not available
Role: distributor
British Geological Survey
Enquiries
email: not available
Role: point of contact

Data Quality

Cave waters, vegetation, rocks and soils were collected through repeat sampling trips to the Cueva-cubío del Llanío cave site throughout 2018 to 2020. Modern calcite was grown on glass plates sited within the cave over time intervals of 6 to 18 months. Water samples were analysed for nitrate content using automated colourimetry. Nitrogen percentage and isotope composition of soils, sediments and vegetation were determined by elemental analyser linked to an isotope ratio mass spectrometer at Lancaster University. The nitrate isotope composition of cave waters and speleothem carbonate were determined using the microbial denitrification of sample nitrate to nitrous oxide gas with subsequent analysis by isotope ratio mass spectrometry within the National Environmental Isotope Facility hosted by the UK Centre for Ecology and Hydrology.
INSPIRE Implementing rules laying down technical arrangements for the interoperability and harmonisation of Geology
Commission Regulation (EU) No 1089/2010 of 23 November 2010 implementing Directive 2007/2/EC of the European Parliament and of the Council as regards interoperability of spatial data sets and services

Constraints

The copyright of materials derived from the British Geological Survey's work is vested in the Natural Environment Research Council [NERC]. No part of this work may be reproduced or transmitted in any form or by any means, or stored in a retrieval system of any nature, without the prior permission of the copyright holder, via the BGS Intellectual Property Rights Manager. Use by customers of information provided by the BGS, is at the customer's own risk. In view of the disparate sources of information at BGS's disposal, including such material donated to BGS, that BGS accepts in good faith as being accurate, the Natural Environment Research Council (NERC) gives no warranty, expressed or implied, as to the quality or accuracy of the information supplied, or to the information's suitability for any use. NERC/BGS accepts no liability whatever in respect of loss, damage, injury or other occurence however caused.
Available under the Open Government Licence subject to the following acknowledgement accompanying the reproduced NERC materials "Contains NERC materials ©NERC [year]"

Metadata about metadata

be32f45f-cbe2-5d1e-e054-002128a47908
British Geological Survey
Environmental Science Centre,Keyworth, NOTTINGHAM, NG12 5GG, United Kingdom
tel: +44 115 936 3100
email: enquiries@bgs.ac.uk
Role: point of contact
2024-04-24

Coupled Resource